yes, it is probabally PC 3200 DDR RAM, it should say on a small label on the side of each stick. It is possible (not likely, but possible if it was a lower-end system) that you have PC 2700 speed.
to run DDR, i strongly strongly reccomend the exact same type of memory, buy the same stuff you've got in there. Brand, model etc. Even that way there can be problems, which is why when you buy the stuff there are options to have them tested for compatibility
Now, how much RAM do you currently have?
Oh, and do a google search for SiSoft Sandra, it will tell you everything you need to know about anything your computer hardware-wise.