Shaun of the Dead?
Oh, you wrotten bastard, you beat me to it.
My picks:
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Hitch - The romance is pretty weak, but Kevin James and Will Smith's interaction is awesome. It's kind of a buddy romantic comedy.
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Big Fish - Not about love, but if she cries, she'll cry during this one. My favorite movie of all time, and definitely a good movie for Valentine's Day.
And then I can jump on board with:
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Shaun of the Dead - It's a romantic comedy. WITH ZOMBIES.
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Philadelphia Story - Again, it's kind of a buddy romantic comedy. Cary Grant and Jimmy Stewart each doing what they do best.
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Love, Actually - My favorite Liam Neeson movie, ever.