Try my hand at a reply here...not sure where it will go.
1. Spiderland - Slint
I haven't seen this mentioned yet, which is a bit surprising. It's a really good album, if short and a little strange.
2. The Dividing - Android Lust
My favourite album made in the last two or three years. It's brilliant and has incredible range for an 'industrial' album.
3. On This Cold Floor - I, Parasite
Loud, angry, moving, sad and just a specatcular album all around. Consider this album and #2 as a matched set, play them back to back.
4. Blue Valentines - Tom Waits
Really, you could go with any Tom Waits album, but this is him at his balladeer best and far more accessible to start with than something like Bone Machine or Mule Variations.
5. VIVIsectVI - Skinny Puppy
I sorta feel I have to put one of there albums on here. This is considered one of the best and is really dynamic, dense and layered for an album of this nature made in the 80's.
6. D.O.A. - Throbbing Gristle
People have mentioned Kraftwerk, and rightfully so. However, you also need to include TG in a list of essential early electronica.
7. Self Titled - Mira
If you dig on My Bloody Valentine, Cocteau Twins, Sundays and a dash of Love Spirals Downwards. This is really great shoe-gazer dreaminess from Florida.
8. Defiance - Assemblage 23
As far as current synthpop/EBM goes, eschew the VNV Nation(much as I like them) and go for this album. It's a standout from start to finish and more mellow than Tom Shear's other three efforts.
9. Louder than Bombs - The Smiths
Most people go for Queen is Dead. This however, is my favourtie in their catalogue. Why? Because it has Shoplifters of the World Unite on it. Petty reason? Maybe. But the rest of the album is just as good too.
10. Closer - Joy Division
It's a must have, simple as that.