Sex to Grinderman would be... interesting.
Getting laid to No Pussy Blues would be fantastically ironic.
Heh heh. On the subject of songs with "Pussy" in the title, I've made out to Pussy by the Brazilian Girls many a time. It's just happy fun music that makes people want to get all frisky and such.
But other more conventional fare would have to be:
Herbert - Scale
DePhazz - Death by Chocolate (recommended in the trip hop thread)
Pretty much anything by Nina Simone although some people might find that a little corny
Metric has already probably been mentioned, but I'll mention it again for emphasis
Also In the Bedroom After the War by Stars
Actually what the hell pretty much anyone who has at one time worked with Kevin Drew
Just so y'all know, the "let me put some music on and make you a drink" move is considered retrograde by many modern ladies (and has therefore become the move of choice among retro minded ladies who go to jazz clubs and wear hats). Modern romances tend be conducted with snoggings on landings, or so I'm told.
. . .
My new band will be called Snoggings on Landings.